U/Th Systematics and ages of authigenic carbonates form Hydrate Ridge, Cascadia Margin: Recorders of fluid flow variations.

Teichert, Barbara M. A., Eisenhauer, Anton , Bohrmann, Gerhard, Haase-Schramm, Alexandra, Bock, Barbara and Linke, Peter (2003) U/Th Systematics and ages of authigenic carbonates form Hydrate Ridge, Cascadia Margin: Recorders of fluid flow variations. Geochimica et Cosmochimica Acta, 67 (20). pp. 3845-3857. DOI 10.1016/S0016-7037(03)00128-5.

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Supplementary data:

Abstract

Uranium (U) concentrations and activity ratios (δ 234U) of authigenic carbonates are sensitive recorders of different fluid compositions at submarine seeps of hydrocarbon-rich fluids ("cold seeps") at Hydrate Ridge, off the coast of Oregon, USA. The low U concentrations (mean: 1.3 ± 0.4 μg/g) and high δ 234U values (165-317‰) of gas hydrate carbonates reflect the influence of sedimentary pore water indicating that these carbonates were formed under reducing conditions below or at the seafloor. Their 230Th/ 234U ages span a time interval from 0.8 to 6.4 ka and cluster around 1.2 and 4.7 ka. In contrast, chemoherm carbonates precipitate from marine bottom water marked by relatively high U concentrations (mean: 5.2 ± 0.8 μg/g) and a mean δ 234U ratio of 166 ± 3‰. Their U isotopes reflect the δ 234U ratios of the bottom water being enriched in 234U relative to normal seawater. Simple mass balance calculations based on U concentrations and their corresponding δ 234U ratios reveal a contribution of about 11% of sedimentary pore water to the bottom water. From the U pore water flux and the reconstructed U pore water concentration a mean flow rate of about 147 ± 68 cm/a can be estimated. 230Th/ 234U ages of chemoherm carbonates range from 7.3 to 267.6 ka. 230Th/ 234U ages of two chemoherms (Alvin and SE-Knoll chemoherm) correspond to time intervals of low sealevel stands in marine isotope stages (MIS) 2, 4, 5, 6, 7 and 8. This observation indicates that fluid flow at cold seep sites sensitively reflects pressure changes of the hydraulic head in the sediments. The δ 18O PDB ratios of the chemoherm carbonates support the hypothesis of precipitation during glacial times. Deviations of the chemoherm δ 18O values from the marine δ 18O record can be interpreted as to reflect temporally and spatially varying bottom water and/or vent fluid temperatures during carbonate precipitation between 2.6 and 8.6°C.

Document Type: Article
Keywords: Uranium; carbonates; Hydrate Ridge, Cascadia Margin; RV Sonne; SO143; SO148
Research affiliation: OceanRep > GEOMAR > FB2 Marine Biogeochemistry > FB2-MG Marine Geosystems
Refereed: Yes
Open Access Journal?: No
DOI etc.: 10.1016/S0016-7037(03)00128-5
ISSN: 0016-7037
Projects: TECFLUX, LOTUS, GEOTECHNOLOGIEN, Dynamik globaler Kreisläufe im System Erde
Expeditions/Models/Experiments:
Date Deposited: 12 Sep 2008 15:05
Last Modified: 28 Aug 2017 13:03
URI: http://oceanrep.geomar.de/id/eprint/1941

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