Curium(III) Borate Shows Coordination Environments of Both Plutonium(III) and Americium(III) Borates.

Polinski, Matthew J., Wang, Shuao, Alekseev, Evgeny V., Depmeier, Wulf, Liu, Guokui, Haire, Richard G. and Albrecht-Schmitt, Thomas E. (2012) Curium(III) Borate Shows Coordination Environments of Both Plutonium(III) and Americium(III) Borates. Angewandte Chemie International Edition, 51 (8). pp. 1869-1872. DOI 10.1002/anie.201107956.

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Abstract

The two faces of curium: The first curium borate has been prepared showing a complex structure with coordination environments for CmIII that are found in both PuIII and AmIII borates (see picture). Time‐resolved laser‐induced photoluminescence studies as well as X‐ray diffraction experiments show two distinct CmIII sites with different coordination environments.

Document Type: Article
Research affiliation: OceanRep > The Future Ocean - Cluster of Excellence
Kiel University
Refereed: Yes
Open Access Journal?: No
Publisher: Wiley
Projects: Future Ocean
Date Deposited: 14 May 2014 09:42
Last Modified: 31 Jul 2019 05:20
URI: https://oceanrep.geomar.de/id/eprint/24211

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