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K AsW2O9 , the first member of the arsenate-tungsten bronze family: Synthesis, structure, spectroscopic and non-linear optical properties.
Alekseev, E. V., Felbinger, O., Wu, S. J., Malcherek, T., Depmeier, Wulf, Modolo, G., Gesing, T. M., Krivovichev, S. V., Suleimanov, E. V., Gavrilova, T. A., Pokrovsky, L. D., Pugachev, A. M., Surovtsev, N. V. and Atuchin, V. V. (2013) K AsW2O9 , the first member of the arsenate-tungsten bronze family: Synthesis, structure, spectroscopic and non-linear optical properties. Journal of Solid State Chemistry, 204 . pp. 59-63. DOI 10.1016/j.jssc.2013.04.038.
Full text not available from this repository.Abstract
K[AsW2O9], prepared by high-temperature solid-state reaction, is the first member of the arsenate–tungsten bronze family. The structure of K[AsW2O9] is based on a 3-dimensional (3D) oxotungstate–arsenate framework with the non-centrosymmetric P212121 space group, a=4.9747(3) Å, b=9.1780(8) Å, c=16.681(2) Å. The material was characterized using X-ray diffraction, scanning electron microscopy (SEM), differential scanning calorimetry (DSC), Raman and infrared (IR) spectroscopic techniques. The results of DSC demonstrate that this phase is stable up to 1076 K. Second harmonic generation (SHG) measurements performed on a powder sample demonstrate noticeable (0.1 of LiIO3) non-linear optical (NLO) activity.
Document Type: | Article |
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Additional Information: | Times Cited: 1 Alekseev, Evgeny V. Felbinger, Olivier Wu, Shijun Malcherek, Thomas Depmeier, Wulf Modolo, Giuseppe Gesing, Thorsten M. Krivovichev, Sergey V. Suleimanov, Evgeny V. Gavrilova, Tatiana A. Pokrovsky, Lev D. Pugachev, Alexey M. Surovtsev, Nikolay V. Atuchin, Victor V. |
Keywords: | Bronze, Tungsten, Arsenic, Non-linear optical properties |
Research affiliation: | Kiel University Kiel University > Kiel Marine Science OceanRep > The Future Ocean - Cluster of Excellence |
Refereed: | Yes |
Open Access Journal?: | No |
Publisher: | Elsevier |
Projects: | Future Ocean |
Date Deposited: | 08 Jul 2014 08:48 |
Last Modified: | 23 Sep 2019 22:56 |
URI: | https://oceanrep.geomar.de/id/eprint/24802 |
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