Assignment of absolute configurations of highly flexible linear diterpenes from the brown alga Bifurcaria bifurcata by VCD spectroscopy.

Merten, Christian, Smyrniotopoulos, Vangelis and Tasdemir, Deniz (2015) Assignment of absolute configurations of highly flexible linear diterpenes from the brown alga Bifurcaria bifurcata by VCD spectroscopy. Chemical Communications, 51 (90). pp. 16217-16220. DOI 10.1039/c5cc05659d.

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Abstract

Correct assignment of the stereogenic centers of highly flexible linear diterpenes (LDs) is challenging. Herein we report the first application of VCD spectroscopy for the absolute configuration determination of LDs of algal origin and provide experimental and computational procedures, such as a fragmentation approach, which will facilitate the use of VCD spectroscopy for configuration assignments of LDs.

Document Type: Article
Additional Information: WOS:000364021600016
Keywords: VIBRATIONAL CIRCULAR-DICHROISM; NMR; IR
Research affiliation: OceanRep > GEOMAR > FB3 Marine Ecology > FB3-MN Marine natural products chemistry
Refereed: Yes
Open Access Journal?: No
DOI etc.: 10.1039/c5cc05659d
ISSN: 1359-7345
Projects: RESOLV, Future Ocean
Date Deposited: 27 Nov 2015 10:00
Last Modified: 20 Jun 2018 09:26
URI: http://oceanrep.geomar.de/id/eprint/30380

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