A Mixed Valent Thioantimonate(III,V): [SbS3]3–and [SbS4]3–as bidentate ligands: Solvothermal synthesis and crystal structure of {Mn(dien)2}2[MnSb2S7].

Herzberg, Nicola, Näther, Christian and Bensch, Wolfgang (2012) A Mixed Valent Thioantimonate(III,V): [SbS3]3–and [SbS4]3–as bidentate ligands: Solvothermal synthesis and crystal structure of {Mn(dien)2}2[MnSb2S7]. Zeitschrift für Kristallographie - Crystalline Materials, 227 (8). pp. 552-556. DOI 10.1524/zkri.2012.1478.

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Supplementary data:

Abstract

The new compound {Mn(dien)(2)}(2)[MnSb2S7] (dien = diethylenetriamine) was obtained under solvothermal conditions and crystallizes in the orthorhombic space group Pbca. The main structural motif is the [MnSb2S7](4-) anion being constructed by a [MnS4](6-) tetrahedron, a [(SbS3)-S-III](3-) and a [(SbS4)-S-V](3-) anion. Each thioantimonate anion shares one edge with the Mn2+ centered cation generating the [MnSb2S7](4-) unit. The two independent Mn2+ cations in the two {Mn(dien)(2)}(2+) complexes are in a distorted octahedral environment of two tridentate acting dien molecules. One cation displays the lambda delta-lambda lambda-conformation and the other the delta lambda-lambda delta-conformation. Several intermolecular S center dot center dot center dot H-N bonding interactions are found between the cations and the anions.

Document Type: Article
Research affiliation: Kiel University > Kiel Marine Science
OceanRep > The Future Ocean - Cluster of Excellence
Kiel University
Refereed: Yes
Open Access Journal?: No
DOI etc.: 10.1524/zkri.2012.1478
ISSN: 2194-4946
Projects: Future Ocean
Date Deposited: 12 Jun 2018 10:11
Last Modified: 04 Apr 2019 08:32
URI: http://oceanrep.geomar.de/id/eprint/43324

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