Birch reduction of chlorobenzene in gas-phase hydrated electrons.

Cao, Y., Hockendorf, R. F. and Beyer, M. K. (2008) Birch reduction of chlorobenzene in gas-phase hydrated electrons. International Journal of Mass Spectrometry, 277 (1-3). pp. 206-209. DOI https://doi.org/10.1016/j.ijms.2008.05.025.

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Supplementary data:

Abstract

Reactions of gas-phase hydrated electrons (H2O)n−, n = 30–65, with chlorobenzene are investigated by Fourier transform ion cyclotron resonance mass spectrometry. The clusters lose water molecules via collision and black-body radiation induced dissociation. In addition, chemical reactions with chlorobenzene lead to formation of Cl−(H2O)n and OH−(H2O)n. While the former product is well-known from pulsed radiolysis studies in the bulk, the latter is observed for the first time in gas-phase clusters. It is indicative of a Birch reduction of the aromatic ring, leading to formation of a chloro-cyclohexadienyl radical C6H6Cl.

Document Type: Article
Keywords: Hydrated electron, Birch reduction, FT-ICR mass spectrometry, Radical anion, Hydrogen transfer
Research affiliation: OceanRep > The Future Ocean - Cluster of Excellence
Kiel University
Refereed: Yes
Open Access Journal?: No
DOI etc.: https://doi.org/10.1016/j.ijms.2008.05.025
ISSN: 1387-3806
Projects: Future Ocean
Date Deposited: 15 Oct 2010 08:40
Last Modified: 26 Feb 2019 12:24
URI: http://oceanrep.geomar.de/id/eprint/8978

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