OceanRep
Birch reduction of chlorobenzene in gas-phase hydrated electrons.
Cao, Y., Hockendorf, R. F. and Beyer, M. K. (2008) Birch reduction of chlorobenzene in gas-phase hydrated electrons. International Journal of Mass Spectrometry, 277 (1-3). pp. 206-209. DOI 10.1016/j.ijms.2008.05.025.
Full text not available from this repository.Abstract
Reactions of gas-phase hydrated electrons (H2O)n−, n = 30–65, with chlorobenzene are investigated by Fourier transform ion cyclotron resonance mass spectrometry. The clusters lose water molecules via collision and black-body radiation induced dissociation. In addition, chemical reactions with chlorobenzene lead to formation of Cl−(H2O)n and OH−(H2O)n. While the former product is well-known from pulsed radiolysis studies in the bulk, the latter is observed for the first time in gas-phase clusters. It is indicative of a Birch reduction of the aromatic ring, leading to formation of a chloro-cyclohexadienyl radical C6H6Cl.
Document Type: | Article |
---|---|
Keywords: | Hydrated electron, Birch reduction, FT-ICR mass spectrometry, Radical anion, Hydrogen transfer |
Research affiliation: | OceanRep > The Future Ocean - Cluster of Excellence Kiel University |
Refereed: | Yes |
Open Access Journal?: | No |
Publisher: | Elsevier |
Projects: | Future Ocean |
Date Deposited: | 15 Oct 2010 08:40 |
Last Modified: | 26 Feb 2019 12:24 |
URI: | https://oceanrep.geomar.de/id/eprint/8978 |
Actions (login required)
View Item |
Copyright 2023 | GEOMAR Helmholtz-Zentrum für Ozeanforschung Kiel | All rights reserved
Questions, comments and suggestions regarding the GEOMAR repository are welcomed
at bibliotheksleitung@geomar.de !