Didemnin B: Comparative study and conformational approach in solution.

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Banaigs, B., Jeanty, G., Francisco, C., Jouin, P., Poncet, J., Heitz, A., Cave, A., Prome, J. C., Wahl, Martin and Lafargue, F. (1989) Didemnin B: Comparative study and conformational approach in solution. Tetrahedron, 45 (1). pp. 181-190. DOI 10.1016/0040-4020(89)80045-6.

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Abstract

A comparative study of isodideimnine-1 and didemnin B is presented using spcctroecopic methods, partial degradation and partial synthesis. This leads to the conclusion of the presence of a single depsipeptide, namely didemnin B, with (3S,4R,5S) isostatine instead of the previous statine residue. An attempt to determine the whole conformation in solution of didemnin B by using 2D-NMR is also described.

Document Type: Article
Refereed: Yes
Open Access Journal?: No
Publisher: Elsevier
Date Deposited: 21 Jan 2014 14:46
Last Modified: 13 May 2020 12:56
URI: https://oceanrep.geomar.de/id/eprint/23171

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