Quantification of the CO2 budget and H2O–CO2 systematics in subduction-zone magmas through the experimental hydration of melt inclusions in olivine at high H2O pressure.

Mironov, Nikita, Portnyagin, Maxim , Botcharnikov, Roman, Gurenko, Andrey, Hoernle, Kaj and Holtz, François (2015) Quantification of the CO2 budget and H2O–CO2 systematics in subduction-zone magmas through the experimental hydration of melt inclusions in olivine at high H2O pressure. Earth and Planetary Science Letters, 425 . pp. 1-11. DOI 10.1016/j.epsl.2015.05.043.

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Supplementary data:

Abstract

Highlights

• Melt inclusions from Klyuchevskoy were homogenized at 1150 °C and PH2O=500 MPaPH2O=500 MPa.
• High-P experiments can recover initial H2O and CO2 contents in dehydrated inclusions.
• Isothermal (de)hydration results in linear trend of CO2 and H2O in inclusion glasses.
• Parental Klyuchevskoy magmas contain ∼3800 ppm CO2 and 4–5 wt.% H2O.
• At least 80% of CO2 is slab-derived in the Klyuchevskoy magmas with CO2/Nb ∼3000.

Abstract

Reliable evaluation of CO2 contents in parental arc magmas, which can be preserved in melt inclusions in phenocrysts, is required to verify the proposed efficiency of CO2 recycling at convergent margins. Quantification of bulk CO2 concentration in melt inclusions requires their complete homogenization. Using samples from lavas from the Bulochka vent of Klyuchevskoy Volcano (Kamchatka), we applied a novel experimental approach to homogenize and re-equilibrate naturally dehydrated (<1 wt.% H2O) melt inclusions from high-Fo (85–91 mol.%) olivine. The experiments were performed at temperatures of 1150–1400 °C, pressures of up to 500 MPa, under dry to H2O-saturated conditions and with oxygen fugacity ranging from CCO to QFM+3.3. No homogenization was achieved at dry conditions. Complete dissolution of fluid bubbles (homogenization) in the melt inclusions was achieved at H2O pressures of 500 MPa and temperature of 1150 °C, when water content in the melt inclusions reached 4–5 wt.% H2O. The CO2 content in the homogenized inclusions is 3800±140 ppm3800±140 ppm and CO2/Nb = 3000 ± 420, which are the highest values reported so far for the typical middle-K primitive arc melts and fall within the range of values inferred from the magmatic flux and volcanic gas data for primary arc magma compositions. About 83% of the CO2 in Klyuchevskoy magmas is likely to be derived from the subducting slab and can be attributed to flux melting with a fluid having a CO2/H2O ratio of ∼0.06. The H2O and CO2 contents in the melt inclusions after hydrous experiments were found to correlate positively with each other and negatively with the volume of fluid bubble, reflecting increasing internal pressure in melt inclusions with increasing melt hydration. Therefore, similar trends observed in some natural sets of melt inclusions can be attributed to a partial dehydration of melts after entrapment, operating simultaneously with or following post-entrapment crystallization. Our study implies that the process of post-entrapment dehydration can be completely reversed under high pressure experimental conditions. If temperature, redox conditions and pressure of melt inclusion entrapment can be independently estimated, then our novel experimental approach (homogenization at high H2O pressure) can be used to reconstruct the initial CO2 content and also the entire composition of melt inclusions in olivine, including their initial H2O content, from any type of volcanic rock. With this approach volatiles in ancient lavas can also be determined, expanding our knowledge of volatile recycling further back in Earth history.

Document Type: Article
Additional Information: WOS:000357755300001
Keywords: melt inclusion; olivine; experiment; volatiles; Kamchatka
Research affiliation: OceanRep > GEOMAR > FB4 Dynamics of the Ocean Floor > FB4-MUHS
Refereed: Yes
Open Access Journal?: No
Publisher: Elsevier
Projects: Future Ocean
Date Deposited: 17 Jun 2015 09:50
Last Modified: 19 Dec 2017 12:45
URI: https://oceanrep.geomar.de/id/eprint/28993

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