General structural relationships between rutile-type VO2 and the Magneli-phases V(n)O2(n-1).

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Katzke, H. and Schlogl, R. (2003) General structural relationships between rutile-type VO2 and the Magneli-phases V(n)O2(n-1). Zeitschrift Fur Kristallographie, 218 (6). pp. 432-439. DOI 10.1524/zkri.218.6.432.20725.

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Abstract

The structures of the Magneli-phases VnO2n-1 (3 less than or equal to n less than or equal to 7) are reviewed with respect to their structural relationships to rutile-type VO2. The general expressions for the transformation matrices P and Q = P-1 are derived allowing the prediction of lattice parameters and atomic coordinates for hypothetical structures Of VnO2n-1 with n greater than or equal to 8.

Document Type: Article
Keywords: metal-insulator transition microsyntactic intergrowth crystal-structure vno2n-1 v9o17
Research affiliation: Kiel University
Date Deposited: 24 Jan 2012 06:44
Last Modified: 23 Sep 2019 16:36
URI: https://oceanrep.geomar.de/id/eprint/16199

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