Polinski, Matthew J., Grant, Daniel J., Wang, Shuao, Alekseev, Evgeny V., Cross, Justin N., Villa, Eric M., Depmeier, Wulf, Gagliardi, Laura and Albrecht-Schmitt, Thomas E. (2012) Differentiating between Trivalent Lanthanides and Actinides. Journal of the American Chemical Society, 134 (25). pp. 10682-10692. DOI 10.1021/ja303804r.

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Abstract

The reactions of LnCl3 with molten boric acid result in the formation of Ln[B4O6(OH)2Cl] (Ln = La–Nd), Ln4[B18O25(OH)13Cl3] (Ln = Sm, Eu), or Ln[B6O9(OH)3] (Ln = Y, Eu–Lu). The reactions of AnCl3 (An = Pu, Am, Cm) with molten boric acid under the same conditions yield Pu[B4O6(OH)2Cl] and Pu2[B13O19(OH)5Cl2(H2O)3], Am[B9O13(OH)4]·H2O, or Cm2[B14O20(OH)7(H2O)2Cl]. These compounds possess three-dimensional network structures where rare earth borate layers are joined together by BO3 and/or BO4 groups. There is a shift from 10-coordinate Ln3+ and An3+ cations with capped triangular cupola geometries for the early members of both series to 9-coordinate hula-hoop geometries for the later elements. Cm3+ is anomalous in that it contains both 9- and 10-coordinate metal ions. Despite these materials being synthesized under identical conditions, the two series do not parallel one another. Electronic structure calculations with multireference, CASSCF, and density functional theory (DFT) methods reveal the An 5f orbitals to be localized and predominately uninvolved in bonding. For the Pu(III) borates, a Pu 6p orbital is observed with delocalized electron density on basal oxygen atoms contrasting the Am(III) and Cm(III) borates, where a basal O 2p orbital delocalizes to the An 6d orbital. The electronic structure of the Ce(III) borate is similar to the Pu(III) complexes in that the Ce 4f orbital is localized and noninteracting, but the Ce 5p orbital shows no interaction with the coordinating ligands. Natural bond orbital and natural population analyses at the DFT level illustrate distinctive larger Pu 5f atomic occupancy relative to Am and Cm 5f, as well as unique involvement and occupancy of the An 6d orbitals.

Document Type:	Article
Research affiliation:	Kiel University OceanRep > The Future Ocean - Cluster of Excellence
Refereed:	Yes
Open Access Journal?:	No
Publisher:	American Chemical Society
Projects:	Future Ocean
Date Deposited:	14 May 2014 09:42
Last Modified:	23 Sep 2019 23:21
URI:	https://oceanrep.geomar.de/id/eprint/24209

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