Wang, Shuao, Alekseev, Evgeny V., Depmeier, Wulf and Albrecht-Schmitt, Thomas E. (2012) New Neptunium(V) Borates That Exhibit the Alexandrite Effect. Inorganic Chemistry, 51 (1). pp. 7-9. DOI 10.1021/ic201682s.

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Abstract

A new neptunium(V) borate, K[(NpO2)B10O14(OH)4], was synthesized using boric acid as a reactive flux. The compound possesses a layered structure in which NpV resides in triangular holes, creating a hexagonal-bipyramidal environment around neptunium. This compound is unusual in that it exhibits the Alexandrite effect, a property that is typically restricted to neptunium(IV) compounds.

Document Type:	Article
Research affiliation:	OceanRep > The Future Ocean - Cluster of Excellence Kiel University
Refereed:	Yes
Open Access Journal?:	No
Publisher:	American Chemical Society
Projects:	Future Ocean
Date Deposited:	14 May 2014 09:11
Last Modified:	31 Jul 2019 04:13
URI:	https://oceanrep.geomar.de/id/eprint/24290

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