Wang, Shuao, Diwu, Juan, Alekseev, Evgeny V., Jouffret, Laurent J., Depmeier, Wulf and Albrecht-Schmitt, Thomas E. (2012) Cation Cation Interactions between Neptunyl(VI) Units. Inorganic Chemistry, 51 (13). pp. 7016-7018. DOI 10.1021/ic3009305.

Full text not available from this repository.

Abstract

The boric acid flux reaction of NpO2(ClO4)2 with NaClO4 affords Na[(NpO2)4B15O24(OH)5(H2O)](ClO4)·0.75H2O (NaNpBO-1). NaNpBO-1 possesses a layered structure consisting of double neptunyl(VI) borate sheets bridged by another NpVI site through cation–cation interactions. The sole presence of NpVI in NaNpBO-1 is supported by absorption and vibrational spectroscopy.

Document Type:	Article
Research affiliation:	Kiel University OceanRep > The Future Ocean - Cluster of Excellence
Refereed:	Yes
Open Access Journal?:	No
Publisher:	American Chemical Society
Projects:	Future Ocean
Date Deposited:	14 May 2014 09:11
Last Modified:	24 Sep 2019 00:11
URI:	https://oceanrep.geomar.de/id/eprint/24291

Actions (login required)

View Item