Luehmann, Henning, Naether, Christian, Kogerler, Paul and Bensch, Wolfgang (2014) Solvothermal synthesis and crystal structure of a heterometal- bridged {V15Sb6} dimer: Ni-2(tren)(3)(V15Sb6O42(H2O)(0.5)) (2) Ni(trenH)(2) center dot H2O. Inorganica Chimica Acta, 421 . pp. 549-552. DOI 10.1016/j.ica.2014.07.028.

Full text not available from this repository.

Abstract

The title compound was obtained under solvothermal conditions and the crystal structure features the spherical [V15Sb6O42(H2O)(0.5)](6-) anion as main structural motif. Two anions are joined by a highly unusual [Ni-2(tren)(3)](4+) complex (tren = tris(2-aminoethyl) amine) via a mu-1,7 bridging tren ligand into a dimeric {[Ni-2(tren)(3)(V15Sb6O42(H2O)(0.5))](2)}(4)(+) moiety. An Sb-N interaction between the dimeric units generates a double-chain being directed along the b-axis. Charge compensation of the anionic structure is achieved by the presence of a [Ni(trenH)(2)](4+) complex containing protonated tren ligands. (C) 2014 Elsevier B.V. All rights reserved.

Document Type:	Article
Additional Information:	Times Cited: 0 Kogerler, Paul/H-5866-2013 Kogerler, Paul/0000-0001-7831-3953 0
Research affiliation:	Kiel University > Kiel Marine Science OceanRep > The Future Ocean - Cluster of Excellence Kiel University
Refereed:	Yes
Open Access Journal?:	No
Publisher:	Elsevier
Projects:	Future Ocean
Date Deposited:	30 Mar 2015 12:33
Last Modified:	16 Apr 2019 10:54
URI:	https://oceanrep.geomar.de/id/eprint/27815

Actions (login required)

View Item