Teske, Christoph Ludwig and Bensch, Wolfgang (2015) On Mono(dithiocarbamato)-silver(I), AgS2CNH2. Zeitschrift für anorganische und allgemeine Chemie, 641 (6). pp. 1031-1035. DOI doi.org/10.1002/zaac.201500086.

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Abstract

The title compound AgS2CNR2 was prepared from an aqueous alcoholic solution by reaction of dicyanoargentate [Ag(CN)(2)](-) with excess ammoniumdithiocarbamate. It crystallizes in the tetragonal space group I (4) over bar 2d (No. 122) with a = 7.9898(4) and c = 12.1072(7) angstrom, V = 772.89(7) angstrom(3), Z = 8. The crystal structure comprises a 3D tetrahedral network of distorted AgS4 units connected via all vertices thus forming the beta-cristobalite structure type. The dithiocarbaramate ligands extend into the hollow space of the framework. Thermal decomposition starts above 125 degrees C and proceeds with a complex reaction to give finally Ag2S (acanthite).

Document Type:	Article
Additional Information:	Times Cited: 0 Si
Keywords:	Dithiocarbamate Silver Preparation X‐Ray diffraction Thermal decomposition
Research affiliation:	Kiel University Kiel University > Kiel Marine Science OceanRep > The Future Ocean - Cluster of Excellence
Refereed:	Yes
Open Access Journal?:	No
Publisher:	American Medical Association
Projects:	Future Ocean
Date Deposited:	18 Oct 2016 03:46
Last Modified:	23 Sep 2019 22:07
URI:	https://oceanrep.geomar.de/id/eprint/32722

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