Wendt, Michael, Rasmussen, Maren, Näther, Christian and Bensch, Wolfgang (2016) Expansion of Germanato-Polyoxovanadate Cluster Cores: Solvothermal Syntheses and Selected Properties of (trenH2)2[{M(tren)}4V15Ge6O48(H2O)] (M= Co and Zn). Zeitschrift für anorganische und allgemeine Chemie, 643 (2). pp. 155-159. DOI 10.1002/zaac.201600379.

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Abstract

Two germanato-polyoxovanadates with the {V15Ge6O48} cluster core are extended by covalent bonds to four transition metal amine complexes [M(tren)]2+ (M = Co and Zn, tren = tris(2-aminoethyl)amine). The complexes have bonds to terminal atoms of the Ge2O7 units and such expansion of a germanato-polyxovanadate was never observed before. The characterization of these compounds revealed the presence of two protonated tren molecules charge balancing the negative charges of the [{M(tren)}4V15Ge6O48(H2O)]4– anion.

Document Type:	Article
Research affiliation:	Kiel University > Kiel Marine Science OceanRep > The Future Ocean - Cluster of Excellence Kiel University
Refereed:	Yes
Open Access Journal?:	Yes
Publisher:	American Medical Association
Date Deposited:	16 Jan 2018 15:13
Last Modified:	17 May 2019 12:37
URI:	https://oceanrep.geomar.de/id/eprint/41512

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