Herzberg, Nicola, Näther, Christian and Bensch, Wolfgang (2012) A Mixed Valent Thioantimonate(III,V): [SbS3]3–and [SbS4]3–as bidentate ligands: Solvothermal synthesis and crystal structure of {Mn(dien)2}2[MnSb2S7]. Zeitschrift für Kristallographie - Crystalline Materials, 227 (8). pp. 552-556. DOI 10.1524/zkri.2012.1478.

Full text not available from this repository.

Abstract

The new compound {Mn(dien)(2)}(2)[MnSb2S7] (dien = diethylenetriamine) was obtained under solvothermal conditions and crystallizes in the orthorhombic space group Pbca. The main structural motif is the [MnSb2S7](4-) anion being constructed by a [MnS4](6-) tetrahedron, a [(SbS3)-S-III](3-) and a [(SbS4)-S-V](3-) anion. Each thioantimonate anion shares one edge with the Mn2+ centered cation generating the [MnSb2S7](4-) unit. The two independent Mn2+ cations in the two {Mn(dien)(2)}(2+) complexes are in a distorted octahedral environment of two tridentate acting dien molecules. One cation displays the lambda delta-lambda lambda-conformation and the other the delta lambda-lambda delta-conformation. Several intermolecular S center dot center dot center dot H-N bonding interactions are found between the cations and the anions.

Document Type:	Article
Research affiliation:	Kiel University Kiel University > Kiel Marine Science OceanRep > The Future Ocean - Cluster of Excellence
Refereed:	Yes
Open Access Journal?:	No
Publisher:	De Gruyter
Projects:	Future Ocean
Date Deposited:	12 Jun 2018 10:11
Last Modified:	23 Sep 2019 22:03
URI:	https://oceanrep.geomar.de/id/eprint/43324

Actions (login required)

View Item