Wang, Jing, Näther, Christian, Djamil, John and Bensch, Wolfgang (2012) [VO(dien)]2GeS4: Solvothermal Synthesis and Crystal Structure with an Ortho-Thiogermanate as Tetradentate Ligand. Zeitschrift Fur Anorganische Und Allgemeine Chemie, 638 (10). pp. 1452-1456. DOI 10.1002/zaac.201200174.

Full text not available from this repository.

Abstract

The compound [VO(dien)]2GeS4 (1, dien = diethylenetriamine) features an ortho‐thiogermanate anion [GeS4]4–, which acts as tetradentate ligand joining [VO(dien)]2– complexes. The compound was obtained under solvothermal conditions crystallizing in thenon‐centrosymmetric orthorhombic space group Pna21 with a =19.8310(11), b = 8.0814(5), c = 12.0889(9) Å, V = 1937.4(2) Å3 and Z = 4. The V4+ cations are in a distorted octahedral environment of a tridentate dien molecule, one oxygen atom and two sulfur atoms from the [GeS4]4– anion. A three‐dimensional network is generated by hydrogen bonding interactions.

Document Type:	Article
Research affiliation:	Kiel University Kiel University > Kiel Marine Science OceanRep > The Future Ocean - Cluster of Excellence
Refereed:	Yes
Open Access Journal?:	No
Publisher:	American Medical Association
Projects:	Future Ocean
Date Deposited:	12 Jun 2018 10:28
Last Modified:	23 Sep 2019 23:56
URI:	https://oceanrep.geomar.de/id/eprint/43334

Actions (login required)

View Item