Teske, Christoph L. and Bensch, Wolfgang (2010) On Crystal Structure Investigations of α- and β-Ammoniumdithiocarbamate NH4CS2NH2and the Role of Hydrogen Bonding. Zeitschrift für anorganische und allgemeine Chemie, 636 (2). pp. 356-362. DOI 10.1002/zaac.200900378.

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Abstract

Single crystal X‐ray data of the low temperature α‐ and the high temperature β‐modifications of NH4CS2NH2 were collected at 170(2) K and at 310(2) K, respectively and the crystal structures were investigated. The α‐type crystallizes orthorhombically in the space group Pca21 with a = 8.2290(16), b = 5.6234(11), c = 10.694(2) Å, and the β‐type monoclinically in space group Cc with a = 14.7968(14), b = 9.4974(6), c = 9.3610(9) Å and β = 129.119(9)°. The crystal chemical relations between the two modifications are discussed particularly with regard to the hydrogen‐bonding networks.

Document Type:	Article
Research affiliation:	Kiel University Kiel University > Kiel Marine Science OceanRep > The Future Ocean - Cluster of Excellence
Refereed:	Yes
Open Access Journal?:	No
Publisher:	American Medical Association
Projects:	Future Ocean
Date Deposited:	12 Jun 2018 11:05
Last Modified:	23 Sep 2019 23:46
URI:	https://oceanrep.geomar.de/id/eprint/43354

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