Quack, Birgit (2019) Atmosphere-Ocean-Islands-Biogeochemical interactions in the Macaronesian Archipelagos of Cabo Verde, the Canaries and Madeira POS533: 28. February 2019- 22. March 2019 Mindelo (Cabo Verdes) – Las Palmas (Spain) AIMAC. . GEOMAR, Kiel, Germany, 70 pp. DOI 10.2312/cr_pos533.

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Abstract

Poseidon 533 – AIMAC (Atmosphere–ocean–island-biogeochemical interactions in the Macaronesian Archipelagos) investigated the influence of the Cape Verdes, the Canary Islands, and Madeira on the physics, chemistry and biology of the surrounding subtropical North- East Atlantic ocean. The air – sea exchange of halocarbons from marine sources impact tropospheric and stratospheric chemistry, and therewith air quality and human health. High oceanic and atmospheric concentrations of iodinated, brominated and chlorinated methanes are often found near coastlines. In particular, bromoform (CHBr3) was recently detected at unexpectedly high concentrations in seawater of subtropical coasts, e.g. at Miami and Tenerife beaches. Bromoform is produced naturally from macro algae and phytoplankton and is the major marine vector of organic bromine to the atmosphere. Together with dibromomethane (CH2Br2), it is the main contributor to natural stratospheric bromine, involved in ozone depletion. Bromoform is also a major product during disinfection of seawater for many industrial and recreational purposes and during desalination processes. While the bromoform production from phytoplankton generally leads to picomolar concentrations in seawater, macroalgal production yields nanomolar concentrations and disinfection processes involving seawater can increase concentrations to micromolar levels. The latter has led to the occasional application of this compound as tracer for the effluents of power plants and wastewater discharges. Other disinfection by-products (DBP) in the effluents can lead to unfavorable effects on the environment and human health. As bromoform shows large concentrations in urbanized and industrialized regions, the elevated concentrations at many coasts may have a major and increasing contribution to the global budget.. We hypothesize, that populated coastlines show elevated bromoform concentrations from disinfection activities, related to the amount of population and industrial activities. Coastal alongshore currents may additionally trap the compound inshore. Therefore, bromoform can be a good tracer of the terrestrial and anthropogenic signal in the island mass effect, which describes the increase in nutrients and biological productivity in the surrounding water masses of an island. POS533 investigated the bromoform distribution in ocean and atmosphere in the subtropical East Atlantic and the islands of Madeira, Tenerife, Gran Canaria and the Cape Verde Archipelago, considering physical and biogeochemical parameters, phytoplankton distribution and carbon chemistry. During the cruise new scientific tools where applied, to differentiate between the islands natural and anthropogenic interactions with ocean and atmosphere. The measurements deliver the first comprehensive biogeochemical data set of phytoplankton, microbiology, trace gases, carbon, oxygen and nutrient cycling from this region close the islands in exchange with the open ocean. Despite the novel knowledge, current climate chemistry and chemical transport models used to understand the anthropogenic signal of marine halocarbon emissions and their effects on tropospheric oxidation and stratospheric ozone will benefit from the expedition's dataset.

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