Müller, Jens Daniel, Gruber, N., Carter, B., Feely, R., Ishii, M., Lange, Nico, Lauvset, S. K., Murata, A., Olsen, A., Pérez, F. F., Sabine, C., Tanhua, Toste , Wanninkhof, R. and Zhu, D. (2023) Decadal Trends in the Oceanic Storage of Anthropogenic Carbon From 1994 to 2014. AGU Advances, 4 (4). Art.Nr. e2023AV000875. DOI 10.1029/2023AV000875.

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Abstract

The oceanic uptake and resulting storage of the anthropogenic CO2 (Cant) that humans have emitted into the atmosphere moderates climate change. Yet our knowledge about how this uptake and storage has progressed in time remained limited. Here, we determine decadal trends in the storage of Cant by applying the eMLR(C*) regression method to ocean interior observations collected repeatedly since the 1990s. We find that the global ocean storage of Cant grew from 1994 to 2004 by 29 ± 3 Pg C dec−1 and from 2004 to 2014 by 27 ± 3 Pg C dec−1 (±1σ). The storage change in the second decade is about 15 ± 11% lower than one would expect from the first decade and assuming proportional increase with atmospheric CO2. We attribute this reduction in sensitivity to a decrease of the ocean buffer capacity and changes in ocean circulation. In the Atlantic Ocean, the maximum storage rate shifted from the Northern to the Southern Hemisphere, plausibly caused by a weaker formation rate of North Atlantic Deep Waters and an intensified ventilation of mode and intermediate waters in the Southern Hemisphere. Our estimates of the Cant accumulation differ from cumulative net air-sea flux estimates by several Pg C dec−1, suggesting a substantial and variable, but uncertain net loss of natural carbon from the ocean. Our findings indicate a considerable vulnerability of the ocean carbon sink to climate variability and change.

Key Points:
- The global ocean storage of anthropogenic carbon grew by 29 ± 3 and 27 ± 3 Pg C dec−1 from 1994 to 2004 and 2004 to 2014, respectively
- The change in oceanic storage of anthropogenic carbon relative to the atmospheric CO2 growth decreased by 15 ± 11% from the first to the second decade
- This reduction is attributed to a decrease of the ocean buffer capacity and changes in ocean circulation

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