Stevenson, Emily I., Burton, Kevin W., Parkinson, Ian J., James, Rachael H., Kisakürek, Basak, Tipper, Ed and Bickle, Michael (2024) Calcite Dissolution-Reprecipitation Reactions Are a Key Control on the Sr/Ca, Mg/Ca and δ88/86Sr Compositions of Himalayan River Waters. American Journal of Science (AJS), 324 . Art.Nr.: 16. DOI 10.2475/001c.124202.

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Abstract

Silicate weathering on the continents is thought to play a critical part in regulating global climate on geological time scales but determination of the magnitude of silicate weathering fluxes is frustrated by the complexity of the weathering processes. Here we present analyses of stable Sr-isotopic compositions (delta Sr-88/86) in a suite of river waters and bedloads from the Himalayas in Nepal to establish the lithological controls on delta Sr-88/86 values and the secondary processes that impact carbonate weathering. A control on delta Sr-88/86 values is lithology with the rivers in carbonate-dominated catchments marginally lower (similar to 0.07 parts per thousand) than in silicate-dominated catchments. However, as for Sr-87/Sr-86 ratios, delta Sr-88/86 values of carbonates are altered by silicate-carbonate mineral exchange during metamorphism. The major potential secondary control on delta Sr-88/86 values in Himalayan catchments is precipitation of secondary calcite responsible for the marked elevation of Sr/Ca and Mg/Ca ratios in the waters. We re-evaluate the mechanisms for secondary calcite formation and conclude that a balanced solution and re-precipitation process, driven by the relative instability of the primary Mg-rich calcite, provides a better explanation for the elevated Sr/Ca ratios than simple precipitation from a highly over saturated solution. This solution-re-precipitation process is akin to that invoked to explain diagenesis of deep-sea sediments. The mechanism of secondary calcite formation impacts the distinction of cation inputs from carbonate and silicate minerals. The correlation between delta Sr-88/86 water-calcite fractionations, Sr/Ca partition coefficients and precipitation rates allows the calcite re-precipitation rates to be inferred from the covariation of water delta Sr-88/86 values and Sr/Ca ratios. These rates are very low (<10(-8) mol m(-2) s(-1)) but are consistent with those inferred from field estimates of the amount of calcite re-precipitated, the surface area of carbonate exposed to weathering and the calcite weathering flux. The low precipitation rates are also consistent with previously reported Delta Ca-44/40 isotope fractionations of similar to-0.2 parts per thousand. The calcite reprecipitation rates are comparable to silicate weathering rates previously inferred from Li-isotopic compositions which is consistent with calcite re-precipitation taking place very close to equilibrium following the initial rapid saturation of the fluids by calcite.

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