Pienack, N., Nather, C. and Bensch, Wolfgang (2009) The Inorganic-Organic Hybrid Compound [Mn(trien)](2)SnS4center dot 4H(2)O: Exhibiting a Hitherto Unknown Binding Mode of the [SnS4](4-) Tetrahedron. European Journal of Inorganic Chemistry (12). pp. 1575-1577. DOI 10.1002/chin.200929022.

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Abstract

The compound [Mn(C6H18N4)](2)SnS4center dot 4H(2)O (C6H18N4 = triethylenetetramine) was obtained under solvothermal conditions. In the structure of the [Mn(C6H18N4)](2)SnS4(infinity), chain, two S atoms of the [SnS4](4)(-) anion act. in a hitherto never observed mu(3) bridging mode that connects the Mn2S2N8 di-octahedra. The Mn2+ ions are octahedrally coordinated by four N and two S atoms, and two symmetry-related octahedra share a common S-S edge. Three of the H2O molecules are joined into chains through H-bonding interactions. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

Document Type:	Article
Keywords:	tinsulfur structure elucidation organic-inorganic hybrid composites coordination modes tin sulfide materials crystal-structures solvothermal synthesis spectroscopic properties thiostannates transition complexes ions
Research affiliation:	Kiel University Kiel University > Kiel Marine Science OceanRep > The Future Ocean - Cluster of Excellence
Refereed:	Yes
Open Access Journal?:	No
Publisher:	Wiley
Projects:	Future Ocean
Date Deposited:	11 Feb 2011 12:15
Last Modified:	23 Sep 2019 23:41
URI:	https://oceanrep.geomar.de/id/eprint/9643

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